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Synlett 2001; 2001(Special Issue): 0907-0909
DOI: 10.1055/s-2001-14663
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On the Source of Transfer of Stereochemical Information in Ligands for Pd-Catalyzed AAA Reactions

Barry M. Trost* , Jorge L. Zambrano, Wolfgang Richter
  • *Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA; Fax + 1 650 7 25 00 02; E-mail: bmt@stanford.edu
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Publication Date:
31 December 2001 (online)

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Examination of a series of ligands for a Pd-catalyzed asymmetric allylic alkylation (AAA) suggests the importance of buttressing effects for creating chiral space for high enantioselectivity.

asymmetric catalysis - palladium catalysis - allylic alkylation - desymmetrization of meso diol derivatives - chiral bis-phosphine ligands

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