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Synlett 2001; 2001(6): 0791-0792
DOI: 10.1055/s-2001-14622
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o-(o-Iodophenyl)phenylselenenyl Ethers/t-BuLi System as an Alkyllithium Equivalent with Structural Variations

Takashi Ooi* , Daiki Sakai, Mio Takada, Naoki Komatsu, Keiji Maruoka
  • *Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan; Fax + 81-75-753-4041; E-mail: maruoka@kuchem.kyoto-u.ac.jp
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Publication Date:
31 December 2001 (online)

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o-(o-Iodophenyl)phenylselenenyl ethers/t-BuLi system can function as an alkyllithium equivalent possessing requisite structures based on an anchimeric approach. the synthetic utility as well as the limitation were evaluated in the in situ trapping reaction with carbonyl compounds.

aldehydes - alkylation - alkyllithiums - anchimeric approach - selenium compounds