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Synlett 2001; 2001(4): 0541-0543
DOI: 10.1055/s-2001-12338
DOI: 10.1055/s-2001-12338
letter
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Utilization of o-[(E)-2-Trimethylsilyl-2-iodovinyl]phenylthio Derivatives as Carbon Radical Precursors by Anchimeric Approach
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Publikationsdatum:
31. Dezember 2001 (online)
o-[(E)-2-Trimethylsilyl-2-iodovinyl]phenylthio derivatives have been introduced as effective precursors for the generation of carbon centered radicals even in the presence of certain nucleophiles; this provides useful information about the structural requirement for inducing an efficient anchimeric effect under mild conditions.
anchimeric effect - carbon radicals - cyclizations - reductions - vinyl iodides