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Synlett 2001; 2001(4): 0541-0543
DOI: 10.1055/s-2001-12338
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Utilization of o-[(E)-2-Trimethylsilyl-2-iodovinyl]phenylthio Derivatives as Carbon Radical Precursors by Anchimeric Approach

Takashi Ooi* , Mayumi Furuya, Daiki Sakai, Yasutoshi Hokke, Keiji Maruoka
  • *Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan; Fax + 81-75-753-4041; E-mail: maruoka@kuchem.kyoto-u.ac.jp
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Publication Date:
31 December 2001 (online)

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o-[(E)-2-Trimethylsilyl-2-iodovinyl]phenylthio derivatives have been introduced as effective precursors for the generation of carbon centered radicals even in the presence of certain nucleophiles; this provides useful information about the structural requirement for inducing an efficient anchimeric effect under mild conditions.

anchimeric effect - carbon radicals - cyclizations - reductions - vinyl iodides