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Synlett 2001; 2001(3): 0430-0432
DOI: 10.1055/s-2001-11393
DOI: 10.1055/s-2001-11393
letter
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Highly Selective Cross Metathesis with Acrylonitrile Using a Phosphine Free Ru-Complex
Further Information
Publication History
Publication Date:
31 December 2001 (online)
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The exchange of the PCy3 ligand in complex 2 by an o-isopropyl-phenylether ligand leads to the extremely stable and highly selective initiator 3 for cross metathesis reactions. For the first time, Ru-catalysed cross coupling with acrylonitrile can be performed in good yields.
alkenes - carbene complexes - cross coupling - metathesis - ruthenium