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Synlett 2001; 2001(2): 0263-0265
DOI: 10.1055/s-2001-10787
DOI: 10.1055/s-2001-10787
letter
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A Novel Method for Direct Construction of Indole Skeletons by Intramolecular Carbopalladation of Allenes Followed by Nucleophilic Substitution
Further Information
Publication History
Publication Date:
31 December 2001 (online)
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Upon treatment with a palladium catalyst, (o-iodoanilinoalkyl)allene compounds undergo intramolecular carbopalladation of allenes followed by intramolecular amination of π-allylpalladium complexes to afford indole derivatives in fairly good yields.
allenes - arylations - indoles - palladium - substitutions