RSS-Feed abonnieren
Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.
https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000083.xml
Synlett 2000; 2000(12): 1813-1815
DOI: 10.1055/s-2000-8678
DOI: 10.1055/s-2000-8678
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
The Reaction of Phenylselenyl Triflate with Diazo Compounds
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/200012/lookinside/thumbnails/10.1055-s-2000-8678-1.jpg)
The reaction of phenylselenyl triflate with diazo compounds is described. Diazoalkanes, α-diazoketones and α-diazoesters gave the corresponding di(phenylselanyl) derivatives either at 0 °C or at room temperature. α-Diazo-β-dicarbonyl compounds gave selectively di(phenylselanyl) derivatives at -78°C, while they gave a mixture of di(phenylselanyl)- and mono(phenylselanyl) derivatives either at 0°C or at room temperature.
diazo compounds - insertions - selenium - selenoacetals - phenylselenyl triflate