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Synlett 2000; 2000(12): 1775-1776
DOI: 10.1055/s-2000-8673
DOI: 10.1055/s-2000-8673
letter
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CAL-B Catalyzed Enantioselective Synthesis of Cyanohydrins - A Facile Route to Versatile Building Blocks
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
A straightforward process for the preparation of optically active cyanohydrins, important building blocks for the synthesis of drugs and agrochemicals, has been established. Lipase B from Candida antarctica (CAL-B) catalyzes the kinetic resolution of racemic cyanohydrin acetates under mild conditions: optimization of the process led to a user-friendly synthesis of (S)- and (R)-cyanohydrins.
cyanohydrin - lipase - kinetic resolution - Candida antarctica - stereoselective synthesis