Synthesis 2000; 2000(12): 1756-1760
DOI: 10.1055/s-2000-8206
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Dioxolane-Derived Carbanions and Their Reactivity

Silvia Carini* , Vanda Cerè, Francesca Peri, Salvatore Pollicino
  • *Department of Organic Chemistry, "A. Mangini" - University of Bologna, Viale Risorgimento, 4, I-40136 Bologna, Italy; Fax +39 (51) 2 09 36 54; E-mail: pollicin@ms.fci.unibo.it
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Publikationsdatum:
31. Dezember 2000 (online)

The generation of negatively charged species by treatment of dioxolanes with BuLi or via fluorodesilylation, results in the formation of new compounds, by spontaneous cycloelimination or upon quenching with C-electrophiles.