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Synthesis 2000; 2000(12): 1756-1760
DOI: 10.1055/s-2000-8206
DOI: 10.1055/s-2000-8206
paper
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Dioxolane-Derived Carbanions and Their Reactivity
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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The generation of negatively charged species by treatment of dioxolanes with BuLi or via fluorodesilylation, results in the formation of new compounds, by spontaneous cycloelimination or upon quenching with C-electrophiles.
carbanions - β-eliminations - silyl dioxolanes - organometallic reagents - lithium