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Synlett 2000; 2000(11): 1561-1564
DOI: 10.1055/s-2000-7924
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New Routes Toward Drimanes and nor-Drimanes from (-)-Sclareol

Alejandro F. Barrero* , E. J. Alvarez-Manzaneda, Rachid Chahboun, C. González Díaz
  • *Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada, 18071 Granada, Spain; Fax +34 58 24 33 18; E-mail: afbarre@goliat.ugr.es
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Publication Date:
31 December 2000 (online)

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New synthetic strategies to prepare natural drimanes and monocarbocyclic terpenoids from (-)-sclareol (2) are reported. The preparation of natural 9,11-drimen-8α-ol (12) and the first enantiospecific synthesis of marine metabolite fulvanin 2 (1) are described.

terpenoids - marine metabolites - decarboxylation - isocyanates

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