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Synlett 2000; 2000(9): 1241-1244
DOI: 10.1055/s-2000-7163
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Novel Nitro Wang Type Linker for Polymer Support Oligosaccharide Synthesis; Polymer Supported Acceptor

Shino Manabe* , Yoshiaki Nakahara, Yukishige Ito
  • *RIKEN (The Institute of Physical and Chemical Research) Wako, Saitama, 351-0198, Japan
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Publication Date:
31 December 2000 (online)

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A novel linker designed for polymer support oligosaccharide synthesis is described. The nitro group carrying Wang resin type linker was stable under Lewis acidic glycosylation conditions. Selective reduction of the nitro group under the homogenous conditions was accompanied by spontaneous cyclization to release the oligosaccharides from polymer.

carbohydrate - glycosylation - glycopeptide - oligosaccharide - solid-phase synthesis

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