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Synlett 2000; 2000(8): 1151-1153
DOI: 10.1055/s-2000-6769
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Nitroalkylation of Alkyl Iodides via Radical Reaction of Silyl Nitronates

Sunggak Kim* , Joo-Yong Yoon, Chae Jo Lim
  • *Department of Chemistry and Center for Molecular Design and Synthesis, School of Molecular Science (BK21), Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea; Fax + 82-42-869-83 70; E-mail: skim@mail.kaist.ac.kr
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Publikationsdatum:
31. Dezember 2000 (online)

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Radical reaction of alkyl iodides with phenylsulfonyl substituted silyl nitronates in the presence of hexamethylditin at 300 nm afforded C-alkylated nitro compounds.

alkylation - halides - radical reactions - sulfones - tandem reactions