Synlett 2000; 2000(8): 1160-1162
DOI: 10.1055/s-2000-6738
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Bismuth(III) Chloride and Triflate: New Efficient Catalysts for the Aza-Diels-Alder Reaction

Hélène Laurent-Robert* , Bernard Garrigues, Jacques Dubac
  • *Hétérochimie Fondamentale et Appliquée (UMR CNRS 5069), Université Paul-Sabatier, 118 route de Narbonne, 31062 Toulouse Cedex, France; Fax (33) 5 61 55 82 04; E-mail: dubac@iris.ups-tlse.fr
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Bismuth (III) chloride (1) and triflate (2) are exellent catalysts of hetero Diels-Alder reactions of imines 3-6 with diene 7 or dienophiles 8 and 9. A one-pot procedure with in situ production of imine from the corresponding aldehyde and amine was possible using the water stable 2 as a catalyst.