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Synlett 2000; 2000(6): 0899-0901
DOI: 10.1055/s-2000-6702
DOI: 10.1055/s-2000-6702
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Asymmetric Epoxidation of Allylic Alcohols Using Vanadium Complexes of (N)-Hydroxy-[2.2]paracyclophane-4-carboxylic Amides
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Publikationsdatum:
31. Dezember 2000 (online)
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Vanadium complexes of (N)-hydroxy-[2.2]paracyclophane-4-carboxylic amides 3 are catalysts for the asymmetric epoxidation of allylic alcohols with tert-butyl hydroperoxide as terminal oxidant. Up to 71% ee have been obtained with 3 c bearing an adamantyl-substituent at the nitrogen of the hydroxamic ligand.
asymmetric catalysis - epoxidation - vanadium - hydroxamic acids - [2.2]paracyclophane