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Synlett 2000; 2000(7): 0991-0992
DOI: 10.1055/s-2000-6674
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An Efficient Conversion of Allyl Esters to Urethanes with Pd Catalyst

Hiroshi Okumoto* , Satoshi Nishihara, Sinya Yamamoto, Hirokazu Hino, Akihiro Nozawa, Akira Suzuki
  • *Department of Chemical Technology, Kurashiki University of Science and the Arts, 2640 Nishinoura, Tsurajima, Kurashiki 712-8505, Japan; Fax + 81 86 440 1062; E-mail: okmt@chem.kusa.ac.jp
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Publication Date:
31 December 2000 (online)

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Reaction of allyl esters in a proper alcohol with Pd catalyst in the presence of (PhO)2P(O)N3 and NaN3 at 80 °C directly gave urethanes. The reactions in t-BuOH afforded amines protected with Boc.

azides - allyl complexes - urethanes - palladium - catalysis

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