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Synlett 2000; 2000(7): 1052-1054
DOI: 10.1055/s-2000-6666
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The Baeyer-Villiger Oxidation of Ketones Using HMS Supported Peroxycarboxylic Acids

Arnold Lambert* , J. A. Elings, Duncan J. Macquarrie, Graham Carr, James H. Clark
  • *Clean Technology Centre, Department of Chemistry, University of York, Heslington, York YO10 5DD, UK; E-mail: Graham.Carr@solvay.com
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Publikationsdatum:
31. Dezember 2000 (online)

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Hexagonal Mesoporous Silica (HMS) supported peroxycarboxylic acids are efficient reagents in the Baeyer-Villiger oxidation of cyclic and linear ketones to lactones and esters respectively at room temperature in hexane.

Baeyer-Villiger oxidation - supported peroxycarboxylic acid