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Synlett 2000; 2000(3): 385-387
DOI: 10.1055/s-2000-6552
DOI: 10.1055/s-2000-6552
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Catalytic Allylation of Aldehydes with Allyltrimethylsilane Using in situ-Generated Trimethylsilyl Methanesulfonate (TMSOMs) as a Catalyst
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Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/200003/lookinside/thumbnails/10.1055-s-2000-6552-1.jpg)
One-pot allylation reactions of carbonyl compounds with allyltrimethylsilane catalyzed by in situ-generated TMSOMs were carried out. TMSOMs was found to be an efficient catalyst in the allylation of the hydrates of α-keto aldehyde and glyoxylate. In situ-generated TMSOMs also can catalyze the SMS reaction of the aldehydes giving the functionalized homoallylic ethers in good to excellent yields.
catalytic allylation - allyltrimethylsilane - functionalized homoallylic ethers