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Synlett 2000; 2000(3): 361-362
DOI: 10.1055/s-2000-6548
DOI: 10.1055/s-2000-6548
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β-Hydroxy Nitrile and β-Hydroxy Oxime Derivatives of [60]Fullerene by Nucleophilic Ring Cleavage of Fulleroisoxazoline and -Isoxazolidine in the Presence of Methanol
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Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/200003/lookinside/thumbnails/10.1055-s-2000-6548-1.jpg)
Ring cleavage of an isoxazoline and isoxazolidines obtained from 1,3-dipolar cycloaddition of [60]fullerene with N-silyloxynitrones was effected by methoxide and fluoride anions at low temperature especially in the presence of methanol to give bifunctionalized derivatives (a β-hydroxy nitrile and β-hydroxy oximes, respectively).
[60]fullerene - nitrone - ring cleavage - β-hydroxy nitrile - β-hydroxy oxime