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Synlett 2000; 2000(3): 415-417
DOI: 10.1055/s-2000-6531
DOI: 10.1055/s-2000-6531
letter
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The Sequential Ester Dienolate [2,3]-Wittig/3-oxy-Cope Rearrangement. New Access to Substituted α-Keto Esters
Further Information
Publication History
Publication Date:
31 December 2000 (online)
![](https://www.thieme-connect.de/media/synlett/200003/lookinside/thumbnails/10.1055-s-2000-6531-1.jpg)
The dienolate [2,3]-Wittig rearrangement of 2-allyloxy-substituted α,β-unsaturated esters 1a-h afforded 3-alkoxycarbonyl-3-hydroxy-substituted 1,5-hexadienes 4a-h which were transformed to α-keto esters 5a-h via a thermal or Pd(II)-catalyzed oxy-Cope rearrangement. Examples for a domino dienolate [2,3]-Wittig/3-oxy Cope rearrangement and for a domino oxy-Cope rearrangement/ene reaction are reported.
rearrangements - pericyclic reactions - α-keto esters - dienolates - domino reactions