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Synlett 2000; 2000(3): 349-350
DOI: 10.1055/s-2000-6520
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Novel Poly-Michael Reactions by Iron(III) Catalysis

Jens Christoffers* , Heiko Oertling, Michael Leitner
  • *Technische Universität Berlin, Institute für Organische Chemie und Technische Chemie, Sekretariat C 3, Straße des 17. Juni 135, D-10623 Berlin, Germany; Fax +49 30/7 23 12 33; E-mail: jchr@wap0105.chem.tu-berlin.de
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Publication Date:
31 December 2000 (online)

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Iron(III) catalyzed conversion of bis-β-keto esters with bis-vinyl ketones furnished a poly-Michael addition product with a weight average molecular weight of Mw = 6 · 103 g/mol and Mw/Mn = 1.7 and a constitution bearing carbonyl moieties all along the polymer backbone.

catalysis - iron - ketones - Michael additions - polymers