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Synlett 2000; 2000(2): 242-244
DOI: 10.1055/s-2000-6500
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Diastereoselective Pentadienylation Reaction of Protected Chiral α-Amino Aldehydes

Frédéric Minassian* , Nadia Pelloux-Léon, Yannick Vallée
  • *LEDSS, UMR CNRS-Université Joseph Fourier, B.P. 53X, 38041 Grenoble, France; Fax +33 4 76 51 43 82; E-mail: yannick.vallee@ujf-grenoble.fr
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Publication Date:
31 December 2000 (online)

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Diastereoselective pentadienylation of chiral α-amino aldehydes was achieved. The obtained anti amino alcohols can be transformed into dienic imines which undergo Diels-Alder cyclisation to give stereoselectively indolizidines.

chiral α-amino aldehydes - pentadienylation - Diels-Alder reaction - indolizidines