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Synlett 2000; 2000(1): 73-74
DOI: 10.1055/s-2000-6444
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A Stereoselective Synthesis of Primary (Z)-Enecarbamates from α-Amidoalkylphenyl Sulfones

Tiziana Mecozzi* , Marino Petrini
  • *Dipartimento di Scienze Chimiche, Università di Camerino, via S. Agostino, 1, I-62032 Camerino, Italy; Fax + 39 737 63 73 45; E-mail: petrini@camserv.unicam.it
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Publication Date:
31 December 2000 (online)

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A base assisted elimination of phenylsulfinic acid from α-amidoalkylphenyl sulfones leads to the synthesis of the corresponding enecarbamates. The Z stereoisomer of the enecarbamate is preferentially formed.

sulfones - enecarbamates - base catalysis - elimination

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