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Synlett 1999; 1999(S1): 987-990
DOI: 10.1055/s-1999-3110
DOI: 10.1055/s-1999-3110
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An Efficient Formal Total Synthesis of (±-Stypoldione via Photochemically Triggered Biomimetic Cyclizations of Terpenoid Polyalkenes
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Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synlett/1999Sup1/lookinside/thumbnails/10.1055-s-1999-3110-1.jpg)
A novel and efficient synthesis of stypoldione, an antitumoral marine toxin, is accomplished by the application of photoinduced biomimetic cyclizations of terpenoid polyalkenes as the key step for the construction of the 6-6-6 tricyclic diterpene part of this natural product.
electron transfer - photochemistry - biomimetic radical cyclization - radical cation - (±)-stypoldione synthesis