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Synlett 1999; 1999(S1): 889-892
DOI: 10.1055/s-1999-3102
DOI: 10.1055/s-1999-3102
letter
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4-Diazocyclohexa-2,5-dienone Derivatives as Photoaffinity Labels for Proteins: Scope and Limitations
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Publication History
Publication Date:
31 December 1999 (online)
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4-Diazocyclohexa-2,5-dienone derivatives are presented as photosensitive reagents generating reactive carbene species which allow efficient photo-coupling reactions with proteins. However, during such coupling reactions, the photogenerated hydroquinones can initiate undesired redox side reactions.
photochemistry - carbenes - hydroquinones - redox reaction