Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000083.xml
Synlett 1999; 1999(S1): 881-884
DOI: 10.1055/s-1999-3100
DOI: 10.1055/s-1999-3100
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
The Sakurai Reaction of 4-Acetoxycyclopentenone - Synthesis of trans-3-Allyl-4-vinylcyclopentanone
Further Information
Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synlett/1999Sup1/lookinside/thumbnails/10.1055-s-1999-3100-1.jpg)
The Sakurai reaction of 4-acetoxycyclopentenone 1a leads to the aldol 2 and the bicyclic product 3. Retroaldol reaction leads to 4-allylcyclopentenone 7, from which the title compounds 9 was prepared in 28% overall yield. Further transformations of 3 are reported.
allyltrimethylsilane - 4-acetoxycyclopentenone - aldol products - 5-trimethylsilyl-bicyclo[3.3.0]octan-1-one - stereoelectronic control