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Synlett 1999; 1999(12): 1987-1989
DOI: 10.1055/s-1999-2996
DOI: 10.1055/s-1999-2996
letter
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Asymmetric Synthesis of Homoallylamines by Nucleophilic Addition of Chirally Modified Allylboron Reagent to N-Borylimines
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Publication History
Publication Date:
31 December 1999 (online)
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One pot synthesis of enantioenriched homoallylamines from nitriles is described. Chirally modified allylboron reagents reacted with N-borylimines derived from partial reduction of nitriles with LiEt3BH to afford enantioenriched homoallylamines in up to 90% ee.
N-borylimine - homoallylamine - nitrile - LiEt3BH - allylboration