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Synlett 1999; 1999(12): 1867-1870
DOI: 10.1055/s-1999-2986
DOI: 10.1055/s-1999-2986
letter
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CuCN-Mediated Intramolecular Conjugate Additions. Syntheses of Functionalized, cis-Fused Bicyclo[6.3.0]undecanes, Bicyclo[6.4.0]dodecanes, and Bicyclo[7.4.0]tridecanes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
A method for the concise, efficient syntheses of substituted, cis-fused bicyclo[6.3.0]undecane-2,6,10-triones, bicyclo[6.4.0]dodecane-2,6,11-triones, bicyclo[7.4.0]tridecane-2,7,12-triones, and related substances is described.
aldol condensation - (alkenyl)trimethylstannanes - alkylation - copper(I) cyanide - medium-size carbocycles - ruthenium tetroxide