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Synlett 1999; 1999(11): 1790-1792
DOI: 10.1055/s-1999-2957
DOI: 10.1055/s-1999-2957
letter
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Platinum(0)-Catalyzed Diboration of Methylenecyclopropanes with Bis(pinacolato)diboron: A Selective Route to 2,4-Bis(boryl)-1-butenes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199911/lookinside/thumbnails/10.1055-s-1999-2957-1.jpg)
Platinum(0)-catalyzed diboration of methylenecyclopropanes with bis(pinacolato)diboron [(Me4C2O2)B-B(O2C2Me4)] in toluene selectively provided the corresponding 2,4-bis(boryl)-1-butene and its analogs in good yields through the cleavage of the proximal bond of the cyclopropane ring.
diboron - platinum - methylenecyclopropane