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Synlett 1999; 1999(9): 1489-1490
DOI: 10.1055/s-1999-2857
DOI: 10.1055/s-1999-2857
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Ytterbium(III) Triflate as a Recyclable Catalyst for the Selective Atom Economic Oxidation of Benzyl Alcohols to Benzaldehydes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199909/lookinside/thumbnails/10.1055-s-1999-2857-1.jpg)
Ytterbium(III) triflate (10 mol%) was found to catalyse the selective oxidation of a range of simple benzyl alcohols to benzaldehydes in good to excellent yield using a stoichiometric quantity of 69% nitric acid as the oxidant, and where the only by-products were water and oxides of nitrogen. The catalyst can be readily recovered and recycled by a simple evaporative process.
alcohols - aldehydes - catalysis - lanthanides - oxidations