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Synlett 1999; 1999(9): 1491-1494
DOI: 10.1055/s-1999-2856
DOI: 10.1055/s-1999-2856
letter
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Chemoenzymatic and Enantiodivergent Routes to Highly Functionalised Steroidal Nuclei
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).
anionic oxy-Cope rearrangement - Diels-Alder cycloaddition - enantiodivergent synthesis - steroids