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Synlett 1999; 1999(9): 1491-1494
DOI: 10.1055/s-1999-2856
DOI: 10.1055/s-1999-2856
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Chemoenzymatic and Enantiodivergent Routes to Highly Functionalised Steroidal Nuclei
Further Information
Publication History
Publication Date:
31 December 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199909/lookinside/thumbnails/10.1055-s-1999-2856-1.jpg)
The bromobenzene-derived and enantiopure cis-1,2-dihydrocatechol 2 can be elaborated, via Diels-Alder cycloaddition and anionic oxy-Cope rearrangement reactions, to either compound 1 or its enantiomer (ent-1).
anionic oxy-Cope rearrangement - Diels-Alder cycloaddition - enantiodivergent synthesis - steroids