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Synlett 1999; 1999(6): 737-740
DOI: 10.1055/s-1999-2738
DOI: 10.1055/s-1999-2738
letter
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Bis C-Glycosylated Diphenylmethanes for Stable Glycoepitope Mimetics
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
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Bis C-glycosylated diphenylmethanes, in which two sugar units protrude from a diphenylmethane scaffold by C-glycosylated bonds, were synthesized as versatile glycoepitope mimetics using C-glycosylated aryl tins and C-glycosylated benzyl bromides. The synthetic method was applied to the synthesis of a sLeX mimetic. Besides, triphenylphosphine oxide was found to be a crucial additive in the Stille coupling reaction.
Stille coupling reaction - additive - aryl C-glycoside - sialyl Lewis X - mimetic