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Synlett 1999; 1999(6): 735-736
DOI: 10.1055/s-1999-2710
DOI: 10.1055/s-1999-2710
letter
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Eight-Membered Thiocycloether via Indium-Mediated Ring Enlargement
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
The ring expansion of a thiocycloether is studied. Ethyl-4-oxo-thiotetrahydropyran-3-carboxylate was expanded to an eight-membered thiocyclo ether by using indium mediated carbon-carbon bond formation in aqueous medium.
indium - aqueous reaction - ring expansion - heterocycle