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Synlett 1999; 1999(6): 792-794
DOI: 10.1055/s-1999-2701
DOI: 10.1055/s-1999-2701
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.
Towards a Synthesis of Glucidic Phosphoenol Pyruvic Acid Derivatives
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199906/lookinside/thumbnails/10.1055-s-1999-2701-1.jpg)
Two synthetic routes are proposed to prepare phosphoenolpyruvate derivatives of xylose as models of potent phosphoenol pyruvate lyase inhibitors: a Perkow reaction between β-bromo-α-ketoester derivatives of xylose 4 and trimethylphosphite, and a new reaction between α-bromoglycidic ester derivatives of xylose 3 and trimethylphosphite.
phosphoenol pyruvic esters - dialdoxylose - β-bromo α-ketoesters - α-chloroglycidic esters - α-bromoglycidic esters - trimethylphosphite