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Synlett 1999; 1999(4): 477-479
DOI: 10.1055/s-1999-2645
DOI: 10.1055/s-1999-2645
letter
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Electron Deficient Dienes. 2. One Step Synthesis of a Coumarin-Fused Electron Deficient Diene and its Inverse Electron Demand Diels-Alder Reactions with Enamines
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199904/lookinside/thumbnails/10.1055-s-1999-2645-1.jpg)
A coumarin-fused electron deficient diene was prepared by the base-induced reaction of dimethyl glutaconate and salicaldehyde. Its inverse electron demand Diels-Alder reactions with enamines give, after in situ elimination and dehydrogenation, benzocoumarins.
Diels-Alder - inverse electron demand - coumarins - enamines