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Synlett 1999; 1999(4): 474-476
DOI: 10.1055/s-1999-2633
DOI: 10.1055/s-1999-2633
letter
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Stereoselective Synthesis of 2,6-Disubstituted-3,7-dioxabicyclo[3.3.0]octanes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199904/lookinside/thumbnails/10.1055-s-1999-2633-1.jpg)
Dihydrofurans bearing a 3-hydroxymethyl group may be efficiently combined with aldehyde dimethylacetals to provide functionalised 2,6-disubstituted-3,7-dioxabicyclo[3.3.0]octanes in a one pot procedure with high stereocontrol.
vinyl epoxide-dihydrofuran rearrangement - furofuran lignan - cationic cyclisation - cascade reaction