PDF herunterladen
Synlett 1999; 1999(3): 348-350
DOI: 10.1055/s-1999-2604
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Dipolar [3+2] Cycloaddition Reactions with Planar Chiral Arene Tricarbonyl Chromium Complexes: Synthesis of Enantiopure Trisubstituted Pyrrolidines

Barbara Schnell* , Gérald Bernardinelli, E. P. Kündig
  • *Département de Chimie Organique, Université de Genève, 30 quai Ernest Ansermet, CH-12111 Genève 4, Switzerland; Fax +41 (22) 3 28 73 96; E-mail: Peter.Kundig@chiorg.unige.ch
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 1999 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

Methyl acrylates and azomethine ylides linked to a planar chiral arene Cr(CO)3 complex underwent highly diastereoselective [3+2] cycloadditions with regioselectivities that could be controlled by the choice of the Lewis acid. Decomplexation yielded enantiopure pyrrolidines.

dipolar cycloaddition - planar chirality - arene complex - chromium - pyrrolidine