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Synlett 1999; 1999(3): 351-353
DOI: 10.1055/s-1999-2596
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High Pressure Synthesis of New Silicon Containing Heteroatom Analogues of Fused Norbornenes

Srécko I. Kirin* , Frank-Gerrit Klärner, Mirjana Eckert-Maksić
  • *Laboratory of Physical Organic Chemistry, Ruđer Bošković Institute, P.O.B. 1016, HR-10001 Zagreb, Croatia
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Publication Date:
31 December 1999 (online)

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The synthesis of fused norbornene analogues containing silicon and oxygen atoms in bridgehead positions is reported. This novel type of compound can be readily obtained in stereospecific Diels-Alder [4+2] cycloaddition of siloles with oxanorbornene derivatives as appropriate dienophiles by the use of high pressure (9 kbar).

Diels-Alder reaction - high pressure chemistry - 7-oxanorbornenes - 7-silanorbornenes - siloles