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Synlett 1999; 1999(3): 351-353
DOI: 10.1055/s-1999-2596
DOI: 10.1055/s-1999-2596
letter
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High Pressure Synthesis of New Silicon Containing Heteroatom Analogues of Fused Norbornenes
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
![](https://www.thieme-connect.de/media/synlett/199903/lookinside/thumbnails/10.1055-s-1999-2596-1.jpg)
The synthesis of fused norbornene analogues containing silicon and oxygen atoms in bridgehead positions is reported. This novel type of compound can be readily obtained in stereospecific Diels-Alder [4+2] cycloaddition of siloles with oxanorbornene derivatives as appropriate dienophiles by the use of high pressure (9 kbar).
Diels-Alder reaction - high pressure chemistry - 7-oxanorbornenes - 7-silanorbornenes - siloles