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Synlett 1999; 1999(2): 237-239
DOI: 10.1055/s-1999-2582
DOI: 10.1055/s-1999-2582
letter
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Double Ring-Opening Reactions of Bis-Cyclopropanes Promoted by Iron Salts
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
Certain bis-cyclopropanes were prepared from the corresponding dienol silane and, on treatment with ferric salts, were found to undergo two sequential C-C bond cleavages to give products corresponding to overall two carbon ring-expansion. In one case the nature of the product obtained was found to depend upon the types of ferric salts employed.
cyclopropane - ring expansion - iron salts