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Synlett 1999; 1999(2): 240-242
DOI: 10.1055/s-1999-2571
DOI: 10.1055/s-1999-2571
letter
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Synthesis of Polyhydroxylated Decalins; a New Strategy Toward the Total Synthesis of Agarfuran Antifeedants
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Publikationsverlauf
Publikationsdatum:
31. Dezember 1999 (online)
This paper describes a new construction strategy for polyhydroxylated decalinic systems through oxidative furan ring opening of 3-(2′-furyl)-2-carbomethoxycyclohexanedione-4-monoethylene ketal 5. The possible functionalization of the decalinic product 6 aimed at the synthesis of antifeeding agarofuran sesquiterpenes, is demonstrated through the preparation of compounds 2-4.
polyhydroxylated decalins - agarofuran - antifeedants - furan - oxidation