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Synlett 1998; 1998(8): 831-834
DOI: 10.1055/s-1998-3138
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Stereoselective Synthesis of α-C-l-Fucopyranosyl Containing C-Disaccharides

El Djouhar Rekaï* , Gilles Rubinstenn, Jean-Maurice Mallet, Pierre Sinaÿ, Stephan N. Müller, Bernd Giese
  • *Ecole Normale Supérieure, Département de Chimie associé au CNRS, 24 rue Lhomond, 75231 Paris cedex 05, France; Fax + 33(0)1 44 32 33 97; E-mail: Pierre.Sinay@ens.fr
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Publication Date:
31 December 2000 (online)

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A variety of α-C-l-fucopyranosyl containing C-dissaccharides were stereoselectively synthesized by radical coupling of phenyl 3,4-O-isopropylidene-Se-β-l-fucopyranoside onto an appropriate exo-methylene-sugar, which is temporarily tethered.

C-disaccharide - L-fucose - tether - radical cyclisation - Electron Spin Resonance