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Synlett 1998; 1998(12): 1315-1316
DOI: 10.1055/s-1998-1977
DOI: 10.1055/s-1998-1977
letter
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Preparation of Silyl-substituted Dizinciomethanes and Their Reactions with Electrophiles
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199812/lookinside/thumbnails/10.1055-s-1998-1977-1.jpg)
Silyl-substituted bis(bromozincio)methanes (RMe2SiCH(ZnBr)2; R = Me, Ph, and p-MeO-C6H4), prepared from the corresponding dibromides by Pb catalyzed reaction with zinc, reacted stepwise with two different electrophiles, R1X and E+, yielding R1-CH(SiMe2R)-E.
zinc - silicon - dimetal - coupling - palladium