Download PDF
Synlett 1998; 1998(12): 1315-1316
DOI: 10.1055/s-1998-1977
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Preparation of Silyl-substituted Dizinciomethanes and Their Reactions with Electrophiles

Seijiro Matsubara* , Yasuyuki Otake, Takuya Morikawa, Kiitiro Utimoto
  • *Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo, Kyoto 606-8501, Japan; Fax 75-753-4863; E-mail: matsubara@orgrx2.kuic.kyoto-u.ac.jp
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Silyl-substituted bis(bromozincio)methanes (RMe2SiCH(ZnBr)2; R = Me, Ph, and p-MeO-C6H4), prepared from the corresponding dibromides by Pb catalyzed reaction with zinc, reacted stepwise with two different electrophiles, R1X and E+, yielding R1-CH(SiMe2R)-E.

zinc - silicon - dimetal - coupling - palladium

      >