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Synlett 1998; 1998(12): 1414-1416
DOI: 10.1055/s-1998-1960
DOI: 10.1055/s-1998-1960
letter
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Asymmetric α-Alkylation of α,β-Unsaturated Esters. Application to the Synthesis of (R)-Lavandulol, (R)-Sesquilavandulol and Related Trifluoromethyl Compounds
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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Diastereoselective α-alkylation/deconjugation of esters of diacetone D-glucose has been performed and applied to the syntheses of (R)-lavandulol, (R)-sesquilavandulol with de up to 74%. The same reaction performed with trifluoromethyl derivatives was also achieved but without significant diastereoselectivity.
lavandulol - sesquilavandulol - asymmetric alkylation - diacetone D-glucose - trifluoromethyl compounds