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Synlett 1998; 1998(12): 1435-1437
DOI: 10.1055/s-1998-1946
DOI: 10.1055/s-1998-1946
letter
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Sequential Free Radical Reactions with Xanthates: Cyclopentane Ring Annulation
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Publikationsverlauf
Publikationsdatum:
31. Dezember 2000 (online)
![](https://www.thieme-connect.de/media/synlett/199812/lookinside/thumbnails/10.1055-s-1998-1946-1.jpg)
In the presence of electron-rich alkenes, electro- and ambiphilic homoallylic radicals, generated by homolytic decomposition of the corresponding xanthates, undergo annulation with inverse electron-demand, and afford cyclopentane derivatives in moderate to good yields.
radicals - annulations - xanthates - cyclopentane