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Synlett 1998; 1998(9): 971-972
DOI: 10.1055/s-1998-1848
DOI: 10.1055/s-1998-1848
letter
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Reduction of Selenium with BER in Methanol. Application to Synthesis of Dialkyl Selenides
Further Information
Publication History
Publication Date:
31 December 2000 (online)
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Selenium was reduced with borohydride exchange resin (BER) in methanol at room temperature to give probably a selenide exchange resin. It reacted with alkyl halide or tosylate to give dialkyl selenides selectively in a quantitative or high yield without forming toxic hydrogen selenide and/or foul-smelling selenol.
BER - borohydride exchange resin - selenium - dialkyl selenide reduction