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Synlett 1998; 1998(7): 780-782
DOI: 10.1055/s-1998-1763
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1,3-Stereoinduction in Radical Additions to Glyoxylate Imines

Michèle P. Bertrand* , Laurence Feray, Robert Nouguier, Lucien Stella
  • *Laboratoire de Chimie Moléculaire Organique, UMR 6517, Boite 562, Faculté des Sciences St-Jérôme, Université d'Aix-Marseille III, Avenue Normandie-Niemen, 13397 Marseille, Cedex 20, France; Fax (33) 4. 67. 09. 44; E-mail: michele.bertrand@LCMO.u-3mrs.fr
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Publication Date:
31 December 2000 (online)

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Addition of alkyl radicals to the acyclic glyoxylate imine 1 proceeded with a 70 : 30 stereoinduction, even at -78 °C. Addition to the cyclic imine 4b resulted in complete stereocontrol at -40 °C.

glyoxylate imines - stereoinduction - radical addition - α-aminoesters

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