A New Efficient Access to Glycono-1,4-lactones by Oxidation of Unprotected Itols by Catalytic Hydrogen Transfer with RhH(PPh3)4-Benzalacetone System

I. Isaac; G. Aizel; I. Stasik; A. Wadouachi; D. Beaupère

doi:10.1055/s-1998-1705

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Synlett 1998; 1998(5): 475-476
DOI: 10.1055/s-1998-1705

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A New Efficient Access to Glycono-1,4-lactones by Oxidation of Unprotected Itols by Catalytic Hydrogen Transfer with RhH(PPh₃)₄-Benzalacetone System

I. Isaac^* , G. Aizel, I. Stasik, A. Wadouachi, D. Beaupère

^*Université de Picardie Jules Verne-Laboratoire de Chimie Organique, 33 rue St Leu-80039 Amiens Cédex, France

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Publikationsdatum:
31. Dezember 2000 (online)

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Treatment of unprotected pentitols and hexitols with RhH(PPh₃)₄-benzalacetone system leads exclusively to glycono-1,4-lactones in 60-96% yield.

unprotected itols - oxidation - T.C.H - RhH(PPh₃)₄-benzalacetone - glyconolactones